Demonstration of NV-detected <mml:math xmlns:mml="http://www.w3.org/1998/Math/MathML"><mml:mmultiscripts><mml:mi mathvariant="normal">C</mml:mi><mml:mprescripts /><mml:none /><mml:mn>13</mml:mn></mml:mmultiscripts></mml:math> NMR at 4.2 T
نویسندگان
چکیده
The nitrogen-vacancy (NV) center in diamond has enabled studies of nanoscale nuclear magnetic resonance (NMR) and electron paramagnetic with high sensitivity small sample volumes. Most NV-detected NMR (NV-NMR) experiments are performed at low fields. While fields useful many applications, high-field NV-NMR fine spectral resolution, signal sensitivity, the capability to observe a wider range nuclei is advantageous for surface detection, microfluidic, condensed matter aimed probing micro- features. However, only handful above 1 T were reported. Herein, we report $^{13}$C spectroscopy 4.2 T, where NV Larmor frequency 115 GHz. Using an electron-nuclear double technique, successfully detect two samples. analysis linewidth based on dipolar broadening theory Van Vleck shows that observed linewidths from consistent intrinsic sample. For 2 find narrower 44 ppm. This work paves way new applications NV-NMR.
منابع مشابه
SQUID detected NMR and NQR
Ž . The dc Superconducting QUantum Interference Device SQUID is a sensitive detector of magnetic flux, with a typical flux noise of the order 1 mF Hz at liquid helium temperatures. Here F s"r2 e is the flux quantum. In our NMR or 0 0 NQR spectrometer, a niobium wire coil wrapped around the sample is coupled to a thin film superconducting coil deposited on the SQUID to form a flux transformer. W...
متن کاملBrain metabolism in glutamatergic and GABAergic compartments detected by in vivo 13C NMR spectroscopy at 14.1 T
Introduction: The combination of dynamic C NMR spectroscopy and the infusion of C-enriched substrates is a powerful method to probe metabolic fluxes in vivo. The increase in magnetic field opened the opportunity for enhanced sensitivity and spectral resolution, which has been explored to study brain metabolism [1]. We now investigated the metabolism of γ-aminobutyric acid (GABA) in the brain us...
متن کاملSQUID-Detected MRI at 132 T with T1-Weighted Contrast Established at 10 T–300 mT
T1-weighted contrast MRI with prepolarization was detected with a superconducting quantum interference device (SQUID). A spin evolution period in a variable field between prepolarization and detection enabled the measurement of T1 in fields between 1.7 T and 300 mT; T1 dispersion curves of agarose gel samples over five decades in frequency were obtained. SQUID detection at 5.6 kHz drastically r...
متن کاملProbing Arginine Side-Chains and Their Dynamics with Carbon-Detected NMR Spectroscopy: Application to the 42 kDa Human Histone Deacetylase 8 at High pH**
Arginine has a unique role among the 20 standard proteinogenic amino acids. In contrast to other charged amino acid side-chains the charge of arginine side-chains is relatively unaffected by the surrounding environment. As a consequence, arginine provides nature with a reliable means of placing a positive charge at any required position in a biomolecule, such as in active sites or at protein–li...
متن کاملExcited-state spectroscopy of single NV defects in diamond using optically detected magnetic resonance
Using pulsed optically detected magnetic resonance techniques, we directly probe electron-spin resonance transitions in the excited-state of single nitrogen-vacancy (NV) color centers in diamond. Unambiguous assignment of excited state fine structure is made, based on changes of NV defect photoluminescence lifetime. This study provides significant insight into the structure of the emitting 3E e...
متن کاملذخیره در منابع من
با ذخیره ی این منبع در منابع من، دسترسی به آن را برای استفاده های بعدی آسان تر کنید
ژورنال
عنوان ژورنال: Physical review
سال: 2023
ISSN: ['0556-2813', '1538-4497', '1089-490X']
DOI: https://doi.org/10.1103/physrevb.108.045421